- Home
- Search Results
- Page 1 of 1
Search for: All records
-
Total Resources2
- Resource Type
-
00020
- Availability
-
11
- Author / Contributor
- Filter by Author / Creator
-
-
Leone, Stephen R. (2)
-
Neumark, Daniel M. (2)
-
Ross, Andrew D. (2)
-
Balkew, Mikias B. (1)
-
Barreau, Lou (1)
-
Blinov, Svyatoslav (1)
-
Hait, Diptarka (1)
-
Haugen, Eric A. (1)
-
Head-Gordon, Martin (1)
-
Kimberg, Victor (1)
-
Krasnov, Pavel (1)
-
Ridente, Enrico (1)
-
Scutelnic, Valeriu (1)
-
#Tyler Phillips, Kenneth E. (0)
-
#Willis, Ciara (0)
-
& Abreu-Ramos, E. D. (0)
-
& Abramson, C. I. (0)
-
& Abreu-Ramos, E. D. (0)
-
& Adams, S.G. (0)
-
& Ahmed, K. (0)
-
- Filter by Editor
-
-
& Spizer, S. M. (0)
-
& . Spizer, S. (0)
-
& Ahn, J. (0)
-
& Bateiha, S. (0)
-
& Bosch, N. (0)
-
& Brennan K. (0)
-
& Brennan, K. (0)
-
& Chen, B. (0)
-
& Chen, Bodong (0)
-
& Drown, S. (0)
-
& Ferretti, F. (0)
-
& Higgins, A. (0)
-
& J. Peters (0)
-
& Kali, Y. (0)
-
& Ruiz-Arias, P.M. (0)
-
& S. Spitzer (0)
-
& Spitzer, S. (0)
-
& Spitzer, S.M. (0)
-
(submitted - in Review for IEEE ICASSP-2024) (0)
-
- (0)
-
-
Have feedback or suggestions for a way to improve these results?
!
Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
Free, publicly-accessible full text available July 1, 2024
-
Ross, Andrew D. ; Hait, Diptarka ; Scutelnic, Valeriu ; Haugen, Eric A. ; Ridente, Enrico ; Balkew, Mikias B. ; Neumark, Daniel M. ; Head-Gordon, Martin ; Leone, Stephen R. ( , Chemical Science)X-ray Transient Absorption Spectroscopy (XTAS) and theoretical calculations are used to study CCl 4 + prepared by 800 nm strong-field ionization. XTAS simultaneously probes atoms at the carbon K-edge (280–300 eV) and chlorine L-edge (195–220 eV). Comparison of experiment to X-ray spectra computed by orbital-optimized density functional theory (OO-DFT) indicates that after ionization, CCl 4 + undergoes symmetry breaking driven by Jahn–Teller distortion away from the initial tetrahedral structure (T d ) in 6 ± 2 fs. The resultant symmetry-broken covalently bonded form subsequently separates to a noncovalently bound complex between CCl 3 + and Cl over 90 ± 10 fs, which is again predicted by theory. Finally, after more than 800 fs, L-edge signals for atomic Cl are observed, indicating dissociation to free CCl 3 + and Cl. The results for Jahn–Teller distortion to the symmetry-broken form of CCl 4 + and formation of the Cl–CCl+3 complex characterize previously unobserved new species along the route to dissociation.more » « less